Cu9.1Te4Cl3: A Thermoelectric Compound with Low Thermal and High Electrical Conductivity
Anna Vogel,† Thomas Miller,‡ Constantin Hoch,‡ Matthias Jakob,§ Oliver Oeckler,§ and Tom Nilges*,†

†Synthesis and Characterization of Innovative Materials, Department of Chemistry, Technical University Munich (TUM), Lichtenbergstraße 4, 85748 Garching bei Munchen, Germany
‡Department of Chemistry, University of Munich (LMU), Butenandtstraße 5-13, 81377 Munich, Germany
§Faculty of Chemistry and Mineralogy; Institute for Mineralogy, Crystallography and Materials Science, Leipzig University, Scharnhorststraße 20, 04275 Leipzig, Germany
S* Supporting Information

ABSTRACT: Cu9.1Te4Cl3 is a new polymorphic compound in the class of coinage metal polytelluride halides. Copper is highly mobile, which results in multiple order-disorder phase transitions in a limited temperature interval from 240 to 370 K. Mainly as a consequence of thermal transport properties, the compound’s thermoelectric figure of merit reaches values up to ZT = 0.15 in the temperature range between room temperature and 523 K. Its structure is closely related to that of Ag10Te4Br3, another coinage metal polytelluride halide, which represents the first p-n-p-switchable semiconductor approachable by a simple temperature change. The title compound outperforms Ag10Te4Br3 in terms of thermoelectric properties by 1 order of magnitude and therefore acts as a link
between the class of p-n-p compounds and thermoelectric materials.

■ INTRODUCTION
Thermoelectric materials off er various opportunities for “green” energy applications by directly converting waste heat to electric energy. The dimensionless figure of merit ZT is often used as measure of thermoelectric performance. As ZT is
-1
defi ned as S2σκ T, where S is the Seebeck coeffi cient, σ the electrical conductivity, and κ the thermal conductivity, a high Seebeck coeffi cient and electrical conductivity together with low thermal conductivity are requirements for high-perform- ance thermoelectric compounds.1 Hence, narrow-band-gap semiconductors are candidates for high ZT values because of their combination of relatively high Seebeck coeffi cients and low electronic thermal conductivity. Mixed solid ion and electron conductors, like the title compound, are another class of materials frequently investigated as candidates for thermo- electrics. Here, the presence of ion conduction is detrimental to their use in thermoelectric applications, but this fact is often ignored. Our interest to determine the thermoelectric properties of the title compound is aimed at another aspect that is not directly related to energy conversion:
The class of semiconductors designated as p-n-p compounds is a class of materials capable of reversible switching between p- and n-type semiconduction without a change of composition. Potential applications are semi- conductor switches, sensors, or devices reacting reversibly to

temperature or voltage changes.2 These compounds undergo ion-mobility-driven order-disorder phase transitions showing typical phonon softening eff ects. This has been confirmed to be usually accompanied by band gap variation and signifi cant change of the density of states at the Fermi level. As a consequence, this feature leads to an intermediate quasi- metallic state in which valence electron conduction in- creases.3,4 The fi rst representative in the class of p-n-p compounds is the tetramorphic coinage metal polychalcoge- nide halide Ag10Te4Br3.5,6 It undergoes p-n-p-switching accompanied by a huge jump of the Seebeck coeffi cient activated simply by variation of the temperature.2 Other materials exhibiting this behavior are the chalcogenides
3,7-9
AgBiSe2, AgCuS, and Tl2Ag12Se7. In4Se3-x does not undergo a p-n-p switch but it shows similar modulations (changes in the Seebeck value in a small temperature range) of
10,11
the Seebeck coefficient.
The structure of the new compound Cu9.1Te4Cl3 is closely
2-
related to Ag10Te4Br3. Both compounds contain isolated Te ions and predominantly covalently bonded Te-units but show quite different electrical properties. With low thermal and high electrical conductivity, Cu9.1Te4Cl3 outperforms Ag10Te4Br3 in

Received: February 15, 2019

© XXXX American Chemical Society A DOI: 10.1021/acs.inorgchem.9b00453
Inorg. Chem. XXXX, XXX, XXX-XXX

terms of thermoelectric performance. Hence, the new compound is a model system to carve out the features leading to p-n-p switching by comparison with the structurally related p-n-p compound and thus serves as a proof of concept concerning the proposed mechanism. In addition, it serves as a link between p-n-p materials and common thermoelectric compounds.
■ EXPERIMENTAL SECTION
Synthesis. Cu9.1Te4Cl3 was prepared from a 6.1:3:4 mixture of copper (Chempur, 99.999%), copper(I) chloride (Alfa Aesar, 97%), and tellurium (Chempur, 99.999%) on a gram scale. The starting materials were sealed into evacuated silica glass ampules, heated to 1320 K, held at this temperature for 3 h, and quenched in an ice bath. The crude product was fi nely ground and annealed at 660 K for 7 days followed by slow cooling to room temperature. This synthesis route leads to a black crystalline material containing large single crystals of the title compound (major phase), a second copper polychalcogenide halide (polycrystalline material, minor phase), and a few, very small crystals of copper(I) chloride which acted as a starting material and transport agent at the same time (see the Supporting Information for additional information and phase analysis). The main fraction, large single crystals of Cu9.1Te4Cl3, were separated from the minor phases and used for further characterization. Cu9.1Te4Cl3 is stable in air.
XRD Experiments. X-ray powder diff raction phase analysis was used to verify the phase purity of Cu9.1Te4Cl3 separated from the bulk material. Temperature-dependent measurements were performed on a Stoe Stadi P powder diff ractometer equipped with an imaging plate detector and an Eurotherm high temperature device using Mo Kα1 radiation (λ = 0.71069 Å). Low-temperature measurements were performed at 173, 193, 223, 273, and 283 K and high-temperature measurements from 293 to 773 K in 10 K steps. Data are given in Figure 4.
Intensity data of two different crystals (crystal 1 was used for the 440 and 350 K and crystal 2 for the 290 and 200 K measurements) were collected on a Stoe IPDS 2T imaging plate diff ractometer (440 and 350 K measurements) and a Stoe STADIVARI diff ractometer with a Dectris hybrid pixel detector (290 and 200 K measurements) fitted with Mo Kα1 radiation (λ = 0.71069 Å). Temperature- dependent measurements were performed using an Oxford Cryo- stream plus system (290 and 200 K measurements) and a Stoe heating system (440 and 350 K measurements).
The data sets were corrected for Lorentz and polarization eff ects, and a numerical absorption correction based on optimized crystal shapes, derived from symmetry-equivalent refl ections, was applied using the Stoe X-Area12 software. The structures were solved by the charge-fl ipping algorithm13 implemented in the Jana 2006 program suite.14 All space groups were derived from a careful analysis of Laue symmetry and extinction conditions as well as group-subgroup relations leading to a chemically correct structure model. Structure refi nements were performed using the Jana 2006 program.14 Coordinates, anisotropic and third-order anharmonic displacement parameters, and the site occupancy factors (sof) of copper atoms in α-
Measurements of Electrical Conductivity and Seebeck Coeffi cient. Finely ground Cu9.1Te4Cl3 crystals were hot-pressed to a pellet of 15 mm diameter and 1.08 mm thickness reaching 87% of the crystallographic density using a P/O/Weber 10 H hot press tool with a P/O/Weber TRG 1 temperature control unit. The sample was pressed with 12 t in a Maassen MP150 lab press while it was heated to 100 °C during 30 min, kept at this temperature for 1 h, and cooled to room temperature during 3 h. Electrical conductivity and Seebeck coeffi cient were measured simultaneously perpendicular to the pressing direction with a NETZSCH SBA 458 Nemesis under a
-1 continuous argon flow with a rate of 60 mL min . For the determination of the Seebeck coeffi cient, a temperature diff erence of at least ΔT = 2 K was used, and for the determination of the electrical conductivity, a DC current of 50 mA was applied. Three full cycles were measured, as shown in the Supporting Information.
Measurement of Thermal Conductivity. Finely ground Cu9.1Te4Cl3 crystals were pressed with a pressure of 10 t to a pellet of 6 mm diameter and 0.95 mm thickness reaching 90% of the crystallographic density. A self-made wolfram carbide pressure die was used. Thermal diff usivity measurements were performed across the pellet under static helium atmosphere using a Linseis LFA1000 laser- flash device equipped with an InSb detector. A laser power of 280 V was applied. Heat loss and finite pulse corrections were calculated applying Dusza’s model.15 Thermal conductivity was obtained by multiplying the values with the Dulong-Petit heat capacity and the measured density of the pellet, which was determined using Archimedes’ principle.
■ RESULTS AND DISCUSSION
The following section deals with the structural characterization and the determination of the electrical and thermal transport properties of the new copper(I) polychalcogenide halide. Temperature-dependent single-crystal structure determinations at various temperatures are reported in order to get a detailed insight into the structural properties of the new material. Bonding properties are illuminated by Raman spectroscopy. Thermal analysis and measurements of the electrical conductivity and the Seebeck coeffi cient outline thermal and electrochemical properties of Cu9.1Te4Cl3 at various temper- atures.
Thermal Analysis. The thermal behavior of Cu9.1Te4Cl3 was determined by diff erential scanning calorimetry (DSC) in the temperature range of 180-500 K. Four endothermic eff ects at 370, 320, 310, and 240 K can be observed that have been assigned to the α-β, β-β′, β′-γ, and γ-δ phase transitions, respectively. The β-β′ and the β′-γ phase transitions are rather close to each other; hence, it is very diffi cult to separate them. In the following, they are interpreted as one phase transition in two steps, called the β-γ phase transition. Figure 4 A and Table 1 give an overview of the

Table 1. Results from Thermal Analysis of Cu9.1Te4Cl3

Cu9.1Te4Cl3 were refi ned without constraints. Details of the structure determination are given in the Supporting Information. For β- Cu9.1Te4Cl3, the same composition as determined for the α-phase was used, and the overall copper content was restricted to this value.
Raman Spectroscopy. Raman spectra were recorded at 300 K by using a Renishaw inVia RE04 Raman microscope equipped with a
phase transition δ → γ
γ → β β → α
T (onset value) (K) 240
310
370
enthalpy (J g 0.60 0.96 0.82
-1)

Nd:YAG laser (λ = 532 nm) and a CCD detector. In order to avoid decomposition of the sample, a low laser power of 0.05 mW was applied, recording a total number of 300 scans.
Thermal Analyses. A fi nely ground sample of phase pure Cu9.1Te4Cl3 (16.3 mg) was transferred to an aluminum crucible and
-1
was measured with a rate of 5 K h using a Netzsch DSC 200 F3Maia apparatus. All measurements were performed under N2 atmosphere. The thermal eff ects were derived as onset temperatures. Enthalpies were determined by integration.
eff ects observed in the temperature range of 200 to 450 K. As can be seen in Figure S4 in the Supporting Information, all eff ects are reversible and have been measured from diff erent independently prepared samples over two consecutive cycles for each run. The four endothermic eff ects are diff erent regarding the shape of the curves. At 370 and 240 K, the signals are slightly broadened; in contrast, the eff ects at 310 and 320 K are very sharp peaks. Regarding the phase-transition

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enthalpies, all eff ects range in the same magnitude, pointing toward order-disorder phase transitions (second-order-like).
Crystal Structure. Temperature-dependent structure in- vestigations have been performed within the temperature range of 200-440 K. A total number of four measurements have been carried out at 200, 290, 350, and 440 K in order to analyze the structural changes undergoing the observed phase transitions. Four diff erent structures could be identifi ed starting with δ-Cu9.1Te4Cl3 at 200 K to α-Cu9.1Te4Cl3 at 440 K. The structures of the two low temperature polymorphs γ and δ could not be determined reliably at this time. A brief summary of crystallographic details of the two high-temper- ature polymorphs α and β is given in Table 2.

Kagome networks in a perpendicular fashion. The dumbbells are arranged to one-dimensional Te-strands with alternating short and long Te-Te distances (3.20-3.27 and 3.83-3.88 Å) parallel to the stacking direction of the networks (see Figure 1). We found no hint for disorder or diff use scattering in the

Table 2. Crystallographic Data of Polymorphic Cu9.1Te4Br3
α-Cu9.1Te4Cl3 β-Cu9.1Te4Cl3
refi ned composition Cu9.1(2)Te4Cl3 Cu9.1Te4Cl3

-1
molar mass (g mol
) 1194.5
1195.0

crystal size (mm) 0.2 × 0.07 × 0.07 0.2 × 0.07 × 0.07
crystal shape/color block/black block/black
crystal system hexagonal hexagonal
space group P6/mmm (191) P63/mmc (194)
Z 1 8
a (Å) 7.2962(7) 14.5019(11)
c (Å) 7.0940(7) 14.190(11)
V (Å3) 327.05(5) 2584(2)
T (K) 440 350

ρcalc. (g cm
-3
)
6.065
6.1428

diffractometer STOE IPDS 2T STOE IPDS 2T
radiation Mo Kα (0.71069 Å) Mo Kα (0.71069 Å)
μ (mm-1) 23.778 24.087
F(000) 523 4183
θ range (deg) 3.22-33.21 4.02-33.39

hkl range
-11/+11, -11/+10,
-10/+10
-22/+20, -22/+22,
- 21/+21

no. of refl ections 4214 64009
Rint 0.0919 0.1325
data/parameters 212/35 1748/125

R/wR [I > 3σ (I)]
R/wR (all) goodness of fi t
res. elec. dens. max/min
-3
(e Å )
0.0278/0.0589 0.0424/0.0663 1.46
-1.09/+1.48
0.0595/0.0991 0.2174/0.1270 1.65
-1.84 /+1.87
Figure 1. Anionic substructures in Cu9.1Te4Cl3: 3.6.3.6 Cl nets (green spheres) and 63 Te nets (dark blue spheres) are stacked along [001]. Predominantly covalently bonded Te2 dumbbells (light blue spheres) forming linear strands center the six-membered rings of the 3.6.3.6 Cl nets. Displacement parameters are shown with 90% probability.

XRD experiments pointing toward a disorder or tendency

The complex crystal structure is discussed by a separate description of the anion and cation substructures. The structure of Cu9.1Te4Cl3 is closely related to Ag10Te4Cl3 but significant diff erences can be found in the cationic substructure including the transition-metal content and in the type and distribution of covalently bonded Te-units leading to severe deviations in the electronic properties.
Anion Substructure. The Cl- ions are arranged to Kagome 3.6.3.6 nets, whereas discrete Te2- ions form honeycomb 63 networks. The distances d(Te-Te) between 4.14 and 4.26 Å and d(Cl-Cl) between 3.61 and 3.64 Å correspond to slightly more than two times the van der Waals radii according to Pauling (dvdW(Te2-) = 2.06 Å, dvdW(Cl-) = 1.80 Å).16 While there are ideal, high symmetric nets in the high-temperature
within the Te-chain to realize an equidistant arrangement. The displacement parameters of Te are only slightly elongated along the Te-chain axis (see Figure 1, displacements shown at 90% probability level).
The distances are longer than in common covalent Te-Te-
2-
bonds. For instance, in the case of [Te2] dumbbells, they range between 2.70 Å in MgTe217 and 2.86 Å in α-K2Te2,18 while in the infinite Te-chains in elemental tellurium, d(Te- Te) is 2.83 Å.19 Nonetheless, the distances are much shorter than twice the van der Waals radius, which is a first indicator for covalent Te-Te interactions within the strands.
Considering the oxidation states in the anionic substructure, while regarding the present Te2-dumbbell as a proper covalently bonded unit, a formal ionic electron count leads

polymorph, distortions appear at lower temperatures. Both
2-
to (Cu+)9[Te2]
2-
(Te
)2(Cl-). Here d(Te-Te) is elongated,

anion nets are stacked alternately along one direction. Predominantly covalently bonded Te2-dumbbells with dis- tances d(Te-Te) from 3.20 to 3.27 Å interpenetrate the Cl-
leading to a higher formal charge than only -1 per Te atom which results in a small excess of copper and subsequently to the sum formula Cu9.1Te4Cl3 (see Table 2). In Ag10Te4Br3, we

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find a Te4 unit consisting of a fully covalently bonded Te2
2-
dumbbell linearly coordinated by two additional Te -ions. This unit interpenetrates the anionic tellurium network
(see Figure 2, top left part). Within the 63 nets, copper atoms remain disordered on diff erent and not fully occupied sites. Due to the reduced distance between two neighbored 63 Te

resulting in (Ag+)10([Te2]2-
2-
)0.5(Te
)3(Cl-)3. As a result, the
nets caused by (a) the reduced ion radius of the halide ions

silver compound contains a higher amount of transition metal while in Cu9.1Te4Cl3, the ratio of [Te2] dumbbells vs isolated
2-
Te ions is higher.
Cation Substructure. As shown in Figure 2, partially occupied copper positions are located in the voids of the 63
forming the 3.6.3.6 halide nets (precisely: smaller chloride vs larger bromide ions) in the silver and copper compounds and (b) the type and size of cation (copper vs silver ions), the available space for copper ions within the Te 63 net in β- Cu9.1Te4Cl3 is reduced. This is why the space within the 63 Te net, in the center of a six-membered Te ring where the Te chain axis intersect, is not available as a possible site for copper ions. They can therefore not coordinate the covalent Te-units in a linear fashion during cooling and ion ordering, as observed during the β-α order-disorder phase transition in Ag10Te4Br3. As a result, copper atoms are still disordered within the 63 nets in β-Cu9.1Te4Cl3 and cannot fully order at this stage (Figure 1, upper left part). As a second consequence of this fi nding, we assume that a certain disorder (either statistical or dynamical disorder) remains in the two low temperature polymorphs. This will be the case if the interstitial sites within the 63 nets remain occupied.
Two out of the Cu9.1Te4Cl3 polymorphs, the α and β phase, are structurally characterized and reported in this study. There are at least two additional polymorphs below and around room temperature with very complex crystal structures, where the structural and physical properties still need to be determined. During the α-β phase transition, a symmetry reduction by a klassengleiche transition of index 2 and an isomorphic transition of index 4 from space group P6/mmm to P63/mmc takes place connected with the decreasing Cu mobility. The cell volume is multiplied by 8 by doubling all three lattice parameters (see Figure 3). After careful analysis of the data we

Figure 2. Structure sections featuring the predominantly covalent bonded Te strands in β- and α-Cu9.1Te4Cl3 and β- and α-Ag10Te4Br3. Displacement parameters are drawn at the 90% probability level.

Te nets and between the anionic layers surrounding the Te- strands in both high temperature polymorphs of Cu9.1Te4Cl3. In the α-polymorph, copper atoms tend to occupy positions within and in direct neighborhood of the 63 Te nets while the occupation of interstitial sites within the 3.6.3.6 Kagome nets is avoided. This is in contrast to the situation in α-Ag10Te4Br3, where silver ions interpenetrate both anion nets (see Figure 2, bottom right). The copper distribution in α-Cu9.1Te4Cl3 is much more comparable to the silver distribution in β- Ag10Te4Br3, where silver ions are located around and within the 63 Te nets (Ag1 position marked in red in Figure 2) separating the Te4 units. In β-Cu9.1Te4Cl3, the amount of copper positions in the neighborhood of the 63 Te nets is reduced from 12 to 3 partially occupied copper positions forming 3-membered rings below and above the 63 network

Figure 3. Unit cells of α- and β-Cu9.1Te4Cl3. During the α-β phase transition, the cell volume is multiplied by 8 by doubling all cell parameters.

assume that twinning occurs after undergoing the 320 K phase transition (β/β′-γ) associated with an additional symmetry reduction from the hexagonal to the orthorhombic crystal system. Here, the translationengleiche transition of index 3 often leads to 3-fold twins and to a possible space group Cmcm. Reconstructed representations of the reciprocal space suggest that, besides twinning at about 320 K, the unit cell might also be enlarged to a 3 × 3 supercell during the 310 K transition of γ-Cu9.1Te4Cl3. At this point the only information we can derive is that the C entering is maybe lost in δ- Cu9.1Te4Cl3 below

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Figure 4. (A) Results from DSC analysis of Cu9.1Te4Cl3. Section between 200 and 450 K. All thermal eff ects are reversible in consecutive cycles. Selected regions discussed in the text are emphasized in gray. (B) Powder diffraction pattern of all four polymorphs of Cu9.1Te4Cl3. (C and D) Powder diff raction pattern of β- and α-Cu9.1Te4Cl3 and calculated pattern drawn with negative intensities.

240 K. Single crystal structure determination using synchro- tron radiation will be conducted shortly to verify these findings.
Powder Diff raction. Powder diff raction patterns measured at 443, 343, 283, and 173 K correspond to the α-, β-, γ- and δ- polymorphs (Figure 4B). Both the α- and the β-polymorphs fit well with patterns calculated from the single-crystal data (Figure 4, parts C and D). As can be seen in Figure 4, both refl ection patterns show only small deviations, which corroborate that there are only slight changes in the crystal structure as a consequence of ordering of the copper atoms due to the decreasing ion mobility with decreasing temper- ature. Regarding the reflections designating the 210, 202, and 220 reflections around 17 and 22° 2θ in the α-polymorph and the corresponding 420, 404, and 440 refl ections in the β- polymorph, some splitting can be observed. Based on structure chemical considerations and our experience with the silver compound, we assume that this observation is associated with
in the γ-polymorph, the corresponding refl ection is shifted to lower angles, and both reflections are resolved. We assume some distortion of the Te-63-networks here. Due to the expected remaining disorder in the copper substructure of the low temperature polymorphs, we did not perform model calculations, and we intend to determine the low temperature structures instead (therefore we will conduct single crystal structure determination using synchrotron radiation shortly). Furthermore, some additional weak reflections occur in the diff raction patterns of low-temperature polymorphs, substan- tiating further symmetry reduction upon cooling.
Raman Spectroscopy. The occurrence of elongated, predominantly covalent Te-Te-bonds in Cu9.1Te4Cl3 was substantiated by Raman spectroscopy. A broad band was
-1
observed at 121 cm , which can be assigned to the stretching mode of the elongated Te-Te unit, in good agreement with the suggested structure model. Previously published frequen- cies for Te-Te modes in tellurium, polytellurides, and free

the distortion of the Cl Kagome
nets in the β-polymorph.
-1
polytelluride complexes include 170 cm
-1
in Te, 168 cm
in

Whether this assumption is valid has to be verified by additional experiments. Going from the β- to the γ- and δ- polymorph, additional splitting of these refl ections can be observed, indicating further distortion of the Kagome nets with decreasing temperature. In the refl ection pattern of both high- temperature polymorphs (α and β), the 113 and the 226 reflections overlap with the strong 212 reflection at 20° 2θ, but
-1 4-
Ag10Te4Br3, and 160 cm in [Cd4Te12] relating to bond
5,20,21
lengths around 2.8 Å. In the title compound, the predominantly covalently bonded dumbbells form Te-strands with alternating short (3.20-3.27 Å) and long (3.83-3.88 Å) Te-Te distances. The elongation of the bonds leads to lower bonding energies, resulting in smaller frequencies in the Raman spectrum. Cu9.1Te4Cl3 is very sensitive toward decomposition

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Figure 5. Thermoelectric characterization measurements of Cu9.1Te4Cl3 with DSC data (red curves). (A) Electric conductivity. (B) Seebeck coefficient. (C) Thermal conductivity. (D) Calculated fi gure of merit ZT.

during the Raman experiment. Upon a slight increase of the laser power, the compound decomposed and showed a sharp and defined mode of elemental tellurium instead. Details are given in the Supporting Information.
Thermoelectric Properties. The Seebeck coeffi cient and
coefficients between +310 and -940 μV K-1 while undergoing p-n-p switching during the α-β phase transition, whereas Cu9.1Te4Cl3 shows the behavior of a p-type conductor over the whole measured temperature range.2
The thermal conductivity is quite low between 0.4 and 0.6

the electrical conductivity were determined simultaneously
W m-1
-1
K
, which is comparable with the thermal conductivity

between room temperature and 523 K (Figure 5). Besides of the coinage metal polytelluride halide Ag10Te4Br3 (0.27-

slight deviations concerning the first heating step, all values are
-1
0.43 W m
K-1 in the temperature range 250-390 K)2 and

reproducible in three consecutive cycles. Therefore, cycles two and three were used for further evaluation. The Seebeck
-1
coeffi cient of Cu9.1Te4Cl3 at room temperature is 36 μV K ,
-1
and it increases linearly with temperature to 85 μV K at 523 K, which is higher than in the thermoelectric compound Cu2Te in this temperature range by a factor of about 2.22 The
-1
electrical conductivity decreases from 325 S cm at room
-1
temperature to 169 S cm at 523 K. This matches, together with the magnitude of the Seebeck coeffi cient, rather the behavior of a metal than of a semiconductor. While the Seebeck coeffi cient increases more or less linearly with the temperature, the progression of the electrical conductivity shows two points of infl ection around the temperatures of the phase transitions. The electrical conductivity of Cu9.1Te4Cl3 at
298 K is much higher than in the insulator CuCl (8.05 × 10-5
-1
S cm ) but about a magnitude lower than in Cu2Te (around
-1 22,23
103 S cm ). In comparison with the semiconductor Ag10Te4Br3, the electrical conductivity is about 3 orders of magnitude higher but the absolute value of the Seebeck coeffi cient is much lower. Ag10Te4Br3 exhibits Seebeck
about 1 order of magnitude lower than the thermal
-1 -1
conductivity in Cu2Te (between 2 and 4 W m K at
22,24,25
room temperature according to diff erent studies). Since the compound is sensitive to laser light, which had already been noticed in the Raman measurements, the sample showed a slight decomposition tendency during the laser-fl ash measurement. As it was possible to reproduce the values of the fi rst cycle with lower laser power in a smaller temperature range in consecutive cycles, the fi rst cycle was used for further evaluation (for details, see the Supporting Information).
To estimate the lattice thermal conductivity κph, the electronic contribution of the thermal conductivity κel was subtracted from the total thermal conductivity. As can be seen in Figure S6 in the Supporting Information kph and kel contribute equally to the total thermal conductivity. To calculate κel, the Wiedemann-Franz law was used, which is defined as κel = L·T·σ, where L is the Lorenz number (2.44 × 10-8 W Ω K-2), T = absolute temperature, and σ = electrical conductivity.26

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The low thermal conductivity in combination with the relatively high electrical conductivity of Cu9.1Te4Cl3 leads to ZT values from 0.028 at room temperature to 0.15 at 523 K, which is in the same range as in the case of Cu2Te.22 With respect to the fi gure of merit, it outperforms the p-n-p compound Ag10Te4Cl3 (maximum ZT value of 0.017 at 390 K) by 1 order of magnitude. On the other hand, the ZT value should not be over interpreted due to the somehow limited potential of the mixed-conducting title compound as thermo- electric material due to the high ion conductivity. Within our experimental framework, Cu9.1Te4Cl3 shows reproducible results and robustness but this will not be the case in thermoelectric generators after long-term usage.
The unlike behavior of both of the coinage metal polytelluride halides Cu9.1Te4Cl3 and Ag10Te4Br3 regarding electronic properties can be explained by slight deviations in the crystal structure. The structures of polymorphic Cu9.1Te4Cl3 are quite similar (but not isotypic) to those of Ag10Te4Br3 considering the alternate stacking of anion networks interpenetrated by predominantly covalently bonded Te-units parallel to the stacking direction.5 Both compounds

allow such a formation of an equidistant Te-chain within the framework of the given Te- and Br-nets. A possible doubling of the c axis will not solve that problem because only the distance between the two anion nets determines the ability to form such a chain. To induce the formation of the equidistant chain, an increase of the c lattice parameter (or more precisely the distance between the 63 Te and the 3.6.3.6 Br nets) seems to be necessary which might be realized by a substitution of Cl by higher homologues.
In the case of Ag10Te4Br3, there are partial substitutions in the anionic (Br by Cl, I, and Te by S, Se) as well as in the
27-29
cationic substructure (Ag by Cu). In the latter case, Ag was substituted up to 50% by Cu under retention of the Ag10Te4Br3 crystal structure.29 Now it seems intriguing to address the influence of silver substitution in Cu9.1Te4Cl3 on the electrical and thermoelectric properties.
Although the thermoelectric performance of the new compound is not competitive to commercial thermoelectric materials like Bi2Te3, PbTe, and Pb1-xGaxTe reaching ZT values of 0.7-0.9 in the temperature range investigated here, it must be taken into account that the material has not yet been

are tetramorphic and show anisotropic ion conductivity.6
30,31
optimized for any thermoelectric application.
On the basis

Nonetheless, Ag10Te4Br3 shows a signifi cant change in the thermoelectric features undergoing the phase transitions triggered by internal redox processes during the formation of equidistant Te-chains while in Cu9.1Te4Cl3 the thermoelectric properties are changed continuously.2 Reasons are diff erences in the predominantly covalently bonded Te-units and in the cation distribution. In the case of Ag10Te4Br3, predominantly covalently bonded Te4-units consisting of Te2-dumbbells and two additional linear coordinated Te atoms interpenetrate the anionic tellurium network. As can be seen in Figure 2, in the low temperature polymorphs these units are separated by an almost linear coordinating silver position. As a result of the increasing ion mobility, silver tends to leave this site in the high temperature polymorphs leading to oligomerization of the Te- units accompanied by internal redox processes. As a result, an equidistant Te chain is realized. This process is accompanied by a signifi cant increase of the electron mobility along the chain leading to a switch of the type of conductivity from p- to n-type and vice versa.
In Cu9.1Te4Cl3, even in the low temperature polymorphs, all copper positions are scattered around the central [Te2]
dumbbell strand and there is no linear coordinating copper position within the Te-strands. Therefore, no structural frustration or equidistant chain formation takes place under- going the phase transitions.
In a series of substitution experiments in Ag10Te4X3, with X = Cl, Br, I, it was shown that the ability of the formation of the equidistant chain is directly correlated to the distance between two 63 Te nets stacked along the c-axis and thereby the c lattice parameter. It was shown that an optimal stabilization of the polymorphs containing the equidistant Te-chain takes place in Ag10Te4Br2.8I0.2 with c = 15.356(2) Å (equivalent two times the distance between two 63 Te nets).27
As we already discussed earlier, the distance between two neighboring 63 Te nets is smaller in Cu9.1Te4Cl3 than in Ag10Te4Br3 due to the diff erent sizes of the halides as well as the cations. In the case of the title compound, the c parameter is 14.19(1) Å (equivalent to twice the distance between two 63 Te nets) in the β-polymorph while the same distance in Ag10Te4Br3 is 15.374(1) Å at room temperature. In Cu9.1Te4Cl3 the c lattice parameter seems to be too short to
of eff ective-mass modeling, the charge carrier concentration may be optimized by targeted doping. This may enhance the relatively low electrical conductivity of the material and lead to a better thermoelectric performance. Subsequently, nano- structuring (either nanostructuring directly32 or by a second phase33) might be a way to further reduce the still very low thermal conductivity. Another aspect needs to be mentioned here which may render a thermoelectric optimization obsolete. In general, solid ion conductors lack long-term stability if used as thermoelectric materials due to the signifi cant mass transport under thermoelectric operation.
Due to close structural relationship to the p-n-p switching in Ag10Te4Cl3, it might be possible to tune the title material toward the initiation of p-n-p switching.
■ CONCLUSION AND OUTLOOK
The new compound Cu9.1Te4Cl3 contains isolated Cl- and
2-
Te anions in the form of alternately stacked Kagome and honeycomb nets interpenetrated by one-dimensional, predom- inantly covalently bonded Te-strands. Mobile Cu ions coordinate this anion framework in an almost liquid-like fashion. It exhibits very low thermal conductivity in combination with reasonable electric conductivity. Even with its low Seebeck coeffi cient, it outperforms Ag10Te4Br3, which features a Seebeck that is higher by 1 order of magnitude. By improvement of the electrical conductivity via doping, the new material might have the potential to enhance its thermoelectric performance.
Furthermore, the anion substructure of Cu9.1Te4Cl3, precisely the [Te2] dumbbell chain, can be regarded as a Peierls distorted intermediate stage heading for another p-n- p switching material like Ag10Te4Br3. p-n-p switching in Ag10Te4Br3 is induced by the structural frustration and Peierls distortion of an equidistant Te chain toward linear Te4 units. For Cu9.1Te4Cl3, we only observe a chain of [Te2] dumbbells which are not able to undergo a transition to an equidistant stage, mainly due to structural reasons. Via substitution in the cation and anion substructure, it might be possible to induce p-n-p switching in this copper compound by an enlargement of the lattice in the direction of the Peierls distortion.

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Acting as a link between the classes of p-n-p switching compounds and thermoelectric materials, optimization of the properties of Cu9.1Te4Cl3 are needed to push it in either direction.
■ ASSOCIATED CONTENT
S* Supporting Information
The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorg- chem.9b00453.
Phase analysis of the bulk material, additional crystallo- graphic data, DSC data, Raman spectra, and full thermoelectric data including the fi rst measurement cycles (PDF)
Accession Codes
CCDC 1896966-1896967 contain the supplementary crys- tallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.
■ AUTHOR INFORMATION
Corresponding Author
*(T.N.) E-mail: [email protected].
ORCID
Constantin Hoch: 0000-0003-2687-178X Oliver Oeckler: 0000-0003-0149-7066 Tom Nilges: 0000-0003-1415-4265
Notes
The authors declare no competing fi nancial interest.
■ ACKNOWLEDGMENTS
The support by the TUM Graduate School is gratefully acknowledged. Funded by the Deutsche Forschungsgemein- schaft (DFG, German Research Foundation) under Germany’s Excellence StrategyEXC 2089/1-390776260.

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compound 1

I
DOI: 10.1021/acs.inorgchem.9b00453
Inorg. Chem. XXXX, XXX, XXX-XXX